Halogenation Of Alkanes Worksheet ((HOT))
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The relative configuration of the haloalkane is usually obtained by the analysis of the carbon atoms which are not replaced by the halogen atoms. Therefore, the order of halogenation is usually determined by the carbon atoms which are closest to the halogen. In general, it is found that the most substituted carbon is the one which is furthest from the halogen in the molecule. In cyclopropane, a carbon atom has two substituents; one at each side of the ring. Therefore, the carbon closer to the halogen is the less substituted one. This gives the following halogenation order:
Alkanes in the presence of excess halogen and a base will undergo a reductive halogenation to form halogenated alkenes. However, alkenes are generally less reactive than alkyl halides and will undergo reaction more slowly.
Alkanes are highly stable and unreactive chemicals. However, the addition of the halogen or halogens leads to an increase in their reactivity with other organics. Alkanes react with alkali metals such as lithium and sodium, alkali earth metals such as magnesium and calcium, halides such as chloride and bromide, and other alkyl halides to form alkali metals and alkali earth metal halides, alkyl halides, and carbenes. These additions are referred to as substitution reactions.
It is very important to note that the exact composition of fuel is not enough to know the exact composition of its reaction products. For example, gasoline contains benzene and other aromatics that are not produced from petroleum and diesel fuel contains aliphatic hydrocarbons, such as alkanes and alkenes. This will be shown later.
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